| 本文已被：浏览 1552次 下载 1277次 |
码上扫一扫！ |
|
|
| 小花清风藤中金属元素的ICP-MS分析 |
|
张学学1,2,周官1,卢顺光2,胡建忠2,李银霞1,祝梓旋1,刘呈雄1,邹坤1
|
|
1.三峡大学 生物与制药学院 天然产物研究与利用湖北省重点实验室，湖北宜昌 443002;2.水利部 水土保持植物开发管理中心，北京 100038
|
|
| 摘要: |
| 分析了采自中国广西清风藤科植物小花清风藤中13种金属元素的含量。小花清风藤茎叶样品经微波消解处理，采用电感耦合等离子体质谱（inductively coupled plasma massspectrometry,ICP-MS）技术检测。钛、钒、铬、锰、铁、铜、锌、砷、硒、铅10种元素采用普通模式检测；为消除多原子离子的干扰，铝、钴和镍3种元素采用了碰撞/反应池技术（collision/reaction cell technology）检测。结果表明试验条件下，硒元素未检出，各金属元素的方法检出限（3s）在0.083~1.564 μg/L之间，方法精密度（n=8）在0.028%~1.510%之间，加标回收率在90%~110%之间。研究结果为了解小花清风藤中金属元素的种类与含量，进一步开发利用小花清风藤提供了参考。 |
| 关键词: 小花清风藤 茎叶 金属元素 电感耦合等离子体质谱(ICP-MS) |
| DOI：10.14188/j.ajsh.2018.06.005 |
| 分类号:O657.63 |
| 基金项目:水利部水土保持植物开发管理中心合作项目(No. 2017-zg-kj-4/SDHZ2017015；2018-zg-kj-03)；国家自然科学基金青年科学基金项目（81803383） |
|
|
|
ZHANG Xuexue1,2,ZHOU Guan1,LU Shunguang2,HU Jianzhong2,LI Yinxia1,ZHU Zixuan1,LIU Chengxiong1,ZOU Kun1
|
|
1.Hubei Key Laboratory of Natural Products Research and Development, College of Biological and Pharmaceutical Sciences, China Three Gorges University, Yichang 443002, Hubei, China;2.Soil and Water Conservation Centre, the Ministry of Water Resources, Beijing 100038, China
|
| Abstract: |
| The metallic elements of Sabia parviflora Wall. ex Roxb were analyzed. The sample was treated by microwave assisted digestion, and the contents of 10 metallic elements in the sample solution were determined by ICP-MS. The polyatomic ion effects on the determination of Al, Co and Ni were eliminated by collision cell technique. Values of detection limit (3 s) of the method found were in the range of 0.083~1.564 μg/L, RSDs (n=8) in the range of 0.028 %~1.510 %, and values of recovery in the range of 90.0%~110.0%. The results provide a reference for further development and utilization of Sabia parviflora Wall. ex Roxb.. |
| Key words: Sabia parviflora Wall. ex Roxb. stem and leaf metallic element inductively coupled plasma massspectrometry(ICP-MS) |
